$ sudo FREESURFER_HOME=$FREESURFER_HOME ./fs_install_mcr R2019b
… answer y to any installer questions ...
Then I think it should work to find the Matlab libraries by at least start off with setting,
$ export LD_LIBRARY_PATH=$FREESURFER_HOME/MCRv97/bin/glnxa64
Please make sure you have otherwise removed any references to your previous matlab 2020a environment from PATH, LD_LIBRARY_PATH, etc.
- R.